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Beilstein J. Org. Chem. 2014, 10, 832–840, doi:10.3762/bjoc.10.79
Graphical Abstract
Scheme 1: Generation of indazol-3-ylidenes.
Scheme 2: Reaction products of indazol-3-ylidenes in heterocycle synthesis.
Scheme 3: Syntheses of acridines from indazol-3-ylidenes.
Scheme 4: Dimerisation of indazol-3-ylidenes to spiro compounds.
Figure 1: Diagnostic 1H and 13C NMR chemical shifts of the Z and E configuration isomer in CDCl3.
Figure 2: Molecular structure of 14c, displacement parameters are drawn at 50% probability level.
Scheme 5: Rhodium complex formation.
Figure 3: Structure of the cation of 15e, displacement parameters are drawn at 50% probability level.
Scheme 6: Rearrangement of the spiro compounds on heating.
Figure 4: Molecular structure of 16b, displacement parameters are drawn at 50% probability level.